pH is an important property of aerosol particles but is difficult to measure directly. Several studies have estimated the pH values for fine particles in North China winter haze using thermodynamic models (i.e., E-AIM and ISORROPIA) and ambient measurements. The reported pH values differ widely, ranging from close to 0 (highly acidic) to as high as 7 (neutral). In order to understand the reason for this discrepancy, we calculated pH values using these models with different assumptions with regard to model inputs and particle phase states. We find that the large discrepancy is due primarily to differences in the model assumptions adopted in previous studies. Calculations using only aerosol phase composition as inputs (i.e., reverse mode) are sensitive to the measurement errors of ionic species and inferred pH values exhibit a bimodal distribution with peaks between −2 and 2 and between 7 and 10. Calculations using total (gas plus aerosol phase) measurements as inputs (i.e., forward mode) are affected much less by the measurement errors, and results are thus superior to those obtained from the reverse mode calculations. Forward mode calculations in this and previous studies collectively indicate a moderately acidic condition (pH from about 4 to about 5) for fine particles in North China winter haze, indicating further that ammonia plays an important role in determining this property. The differences in pH predicted by the forward mode E-AIM and ISORROPIA calculations may be attributed mainly to differences in estimates of activity coefficients for hydrogen ions. The phase state assumed, which can be either stable (solid plus liquid) or metastable (only liquid), does not significantly impact pH predictions of ISORROPIA.
With the largest installed capacity in the world, wind power in China is experiencing a ∼20% curtailment. The inflexible combined heat and power (CHP) has been recognized as the major barrier for integrating the wind source. The approach to reconcile the conflict between inflexible CHP units and variable wind power in Chinese energy system is yet un-clear. This paper explores the technical and economic feasibility of deploying the heat storage tanks and electric boilers under typical power grids and practical operational regulations. A mixed integer linear optimization model is proposed to simulate an integrated power and heating energy systems, including a CHP model capable of accounting for the commitment decisions and non-convex energy generation constraints. The model is applied to simulate a regional energy system (Jing-Jin-Tang) covering 100-million population, with hourly resolution over a year, incorporating actual data and operational regulations. The results project an accelerating increase in wind curtailment rate at elevated wind penetration. Investment for wind breaks-even at 14% wind penetration. At such penetration, the electric boiler (with heat storage) is effective in reducing wind curtailment. The investment in electric boilers is justified on a social economic basis, but the revenues for different stakeholders are not distributed evenly.
The United States has committed to reduce its greenhouse gas emissions by 26%–28% by 2025 and by 83% by 2050 relative to 2005. Meeting these objectives will require major investments in renewable energy options, particularly wind and solar. These investments are promoted at the federal level by a variety of tax credits, and at the state level by requirements for utilities to include specific fractions of renewable energy in their portfolios (Renewable Portfolio Standards) and by opportunities for rooftop PV systems to transfer excess power to utilities through net metering, allowing meters to operate in reverse. The paper discusses the current status of these incentives.
China hosts the world’s largest market for wind-generated electricity. The financial return and carbon reduction benefits from wind power are sensitive to changing wind resources. Wind data derived from an assimilated meteorological database are used here to estimate what the wind generated electricity in China would have been on an hourly basis over the period 1979 to 2015 at a geographical resolution of approximately 50 km × 50 km. The analysis indicates a secular decrease in generating potential over this interval, with the largest declines observed for western Inner Mongolia (15 ± 7%) and the northern part of Gansu (17 ± 8%), two leading wind investment areas. The decrease is associated with long-term warming in the vicinity of the Siberian High (SH), correlated also with the observed secular increase in global average surface temperatures. The long-term trend is modulated by variability relating to the Pacific Decadal Oscillation (PDO) and the Arctic Oscillation (AO). A linear regression model incorporating indices for the PDO and AO, as well as the declining trend, can account for the interannual variability of wind power, suggesting that advances in long-term forecasting could be exploited to markedly improve management of future energy systems.
In the 21st Conference of the Parties to the UNFCCC held in Paris in December 2015, China pledged to peak its carbon emissions and increase non-fossil energy to 20% by 2030 or earlier. Expanding renewable capacity, especially wind power, is a central strategy to achieve these climate goals. Despite greater capacity for wind installation in China compared to the US (145.1 versus 75.0 GW), less wind electricity is generated in China (186.3 versus 190.9 TWh). Here, we quantify the relative importance of the key factors accounting for the unsatisfactory performance of Chinese wind farms. Different from the results in earlier qualitative studies, we find that the difference in wind resources explains only a small fraction of the present China-US difference in wind power output (17.9% in 2012); the curtailment of wind power, differences in turbine quality, and delayed connection to the grid are identified as the three primary factors (respectively 49.3%, 50.2%, and 50.3% in 2012). Improvements in both technology choices and the policy environment are critical in addressing these challenges.
The climate of our planet is changing at a rate unprecedented in recent human history. The energy absorbed from the sun exceeds what is returned to space. The planet as a whole is gaining energy. The heat content of the ocean is increasing; the surface and atmosphere are warming; mid-latitude glaciers are melting; sea level is rising. The Arctic Ocean is losing its ice cover. None of these assertions are based on theory but on hard scientific fact. Given the science-heavy nature of climate change, debates and discussions have not played as big a role in the public sphere as they should, and instead are relegated to often misinformed political discussions and inaccessible scientific conferences. Michael B. McElroy, an eminent Harvard scholar of environmental studies, combines both his research chops and pedagogical expertise to present a book that will appeal to the lay reader but still be grounded in scientific fact.
In Energy and Climate: Vision for the Future, McElroy provides a broad and comprehensive introduction to the issue of energy and climate change intended to be accessible for the general reader. The book includes chapters on energy basics, a discussion of the contemporary energy systems of the US and China, and two chapters that engage the debate regarding climate change. The perspective is global but with a specific focus on the US and China recognizing the critical role these countries must play in addressing the challenge of global climate change. The book concludes with a discussion of initiatives now underway to at least reduce the rate of increase of greenhouse gas emissions, together with a vision for a low carbon energy future that could in principle minimize the long-term impact of energy systems on global climate.
Development of shale gas resources is expected to play an important role in China's projected transition to a low-carbon energy future. The question arises whether the availability of water could limit this development. The paper considers a range of scenarios to define the demand for water needed to accommodate China's projected shale gas production through 2020. Based on data from the gas field at Fuling, the first large-scale shale gas field in China, it is concluded that the water intensity for shale gas development in China (water demand per unit lateral length) is likely to exceed that in the US by about 50%. Fuling field would require a total of 39.9–132.9 Mm3 of water to achieve full development of its shale gas, with well spacing assumed to vary between 300 and 1000 m. To achieve the 2020 production goal set by Sinopec, the key Chinese developer, water consumption is projected to peak at 7.22 Mm3 in 2018. Maximum water consumption would account for 1% and 3%, respectively, of the available water resource and annual water use in the Fuling district. To achieve China's nationwide shale gas production goal set for 2020, water consumption is projected to peak at 15.03 Mm3 in 2019 in a high-use scenario. It is concluded that supplies of water are adequate to meet demand in Fuling and most projected shale plays in China, with the exception of localized regions in the Tarim and Jungger Basins.
Accommodating variable wind power poses a critical challenge for electric power systems that are heavily dependent on combined heat and power (CHP) plants, as is the case for north China. An improved unit-commitment model is applied to evaluate potential benefits from pumped hydro storage (PHS) and electric boilers (EBs) in West Inner Mongolia (WIM), where CHP capacity is projected to increase to 33.8 GW by 2020. A business-as-usual (BAU) reference case assumes deployment of 20 GW of wind capacity. Compared to BAU, expanding wind capacity to 40 GW would allow for a reduction in CO2 emissions of 33.9 million tons, but at a relatively high cost of US$25.3/ton, reflecting primarily high associated curtailment of wind electricity (20.4%). A number of scenarios adding PHS and/or EBs combined with higher levels of wind capacity are evaluated. The best case indicates that a combination of PHS (3.6 GW) and EBs (6.2 GW) together with 40 GW of wind capacity would reduce CO2 emissions by 43.5 million tons compared to BAU, and at a lower cost of US$16.0/ton. Achieving this outcome will require a price-incentive policy designed to ensure the profitability of both PHS and EB facilities.
Based on assimilated meteorological data for the period January 1979 to December 2010, the origin of wind energy is investigated from both mechanical and thermodynamic perspectives, with special focus on the spatial distribution of sources, historical long term variations and the efficiency for kinetic energy production. The dry air component of the atmosphere acts as a thermal engine, absorbing heat at higher temperatures, approximately 256 K, releasing heat at lower temperatures, approximately 252 K. The process is responsible for production of wind kinetic energy at a rate of 2.46 W/m2 sustaining thus the circulation of the atmosphere against frictional dissipation. The results indicate an upward trend in kinetic energy production over the past 32 years, indicating that wind energy resources may be varying in the current warming climate. This analysis provides an analytical framework that can be adopted for future studies addressing the ultimate wind energy potential and the possible perturbations to the atmospheric circulation that could arise as a result of significant exploitation of wind energy.
The atmosphere is an example of a non-equilibrium system. This study explores the relationship among temperature, energy and entropy of the atmosphere, introducing two variables that serve to quantify the thermodynamic disequilibrium of the atmosphere. The maximum work, Wmax, that the atmosphere can perform is defined as the work developed through a thermally reversible and adiabatic approach to thermodynamic equilibrium with global entropy conserved. The maximum entropy increase, (ΔS)max, is defined as the increase in global entropy achieved through a thermally irreversible transition to thermodynamic equilibrium without performing work. Wmax is identified as an approximately linear function of (ΔS)max. Large values of Wmax or (ΔS)max correspond to states of high thermodynamic disequilibrium. The seasonality and long-term historical variation of Wmax and (ΔS)max are computed, indicating highest disequilibrium in July, lowest disequilibrium in January with no statistically significant trend over the past 32 years. The analysis provides a perspective on the interconnections of temperature, energy and entropy for the atmosphere and allows for a quantitative investigation of the deviation of the atmosphere from thermodynamic equilibrium.
The Hadley system provides an example of a thermally direct circulation; the Ferrel system in contrast provides an example of a thermally indirect circulation. In this study, the authors develop an approach to investigate the key thermodynamic properties of the Hadley and Ferrel systems, quantifying them using assimilated meteorological data covering the period January 1979–December 2010. This analysis offers a fresh perspective on the conversion of energy in the atmosphere from diabatic heating to the production of atmospheric kinetic energy. The results indicate that the thermodynamic efficiency of the Hadley system, considered as a heat engine, has been relatively constant over the 32-yr period covered by the analysis, averaging 2.6%. Over the same interval, the power generated by the Hadley regime has risen at an average rate of about 0.54 TW yr−1; this reflects an increase in energy input to the system consistent with the observed trend in the tropical sea surface temperatures. The Ferrel system acts as a heat pump with a coefficient of performance of 12.1, consuming kinetic energy at an approximate rate of 275 TW and exceeding the power production rate of the Hadley system by 77 TW.