Air Pollution, Greenhouse Gases & Climate

In Press
Xi Yang, Chris P. Nielsen, Shaojie Song, Michael B. McElroy, and Xiaoyang Wang. In Press. “Breaking the “hard-to-abate” bottleneck in China’s path to carbon neutrality.” Nature Energy.
2022
Rong Tang, Jing Zhao, Yifan Liu, Xin Huang, Yanxu Zhang, Derong Zhou, Aijun Ding, Chris Nielsen, and Haikun Wang. 2022. “Air quality and health co-benefits of China's carbon dioxide emissions peaking before 2030.” Nature Communications, 13, 1008. Publisher's VersionAbstract

Recent evidence shows that carbon emissions in China are likely to peak ahead of 2030. However, the social and economic impacts of such an early carbon peak have rarely been assessed. Here we focus on the economic costs and health benefits of different carbon mitigation pathways, considering both possible socio-economic futures and varying ambitions of climate policies. We find that an early peak before 2030 in line with the 1.5  C target could avoid ~118,000 and ~614,000 PM2.5 attributable deaths under the Shared Socioeconomic Pathway 1, in 2030 and 2050, respectively. Under the 2  C target, carbon mitigation costs could be more than offset by health co-benefits in 2050, bringing a net benefit of $393–$3,017 billion (in 2017 USD value). This study not only provides insight into potential health benefits of an early peak in China, but also suggests that similar benefits may result from more ambitious climate targets in other countries.

Shaojie Song, Haiyang Lin, Peter Sherman, Xi Yang, Shi Chen, Xi Lu, Tianguang Lu, Xinyu Chen, and Michael B. McElroy. 2022. “Deep decarbonization of the Indian economy: 2050 prospects for wind, solar, and green hydrogen.” iScience, 25, 6, Pp. 104399. Publisher's VersionAbstract
The paper explores options for a 2050 carbon free energy future for India. Onshore wind and solar sources are projected as the dominant primary contributions to this objective. The analysis envisages an important role for so-called green hydrogen produced by electrolysis fueled by these carbon free energy sources. This hydrogen source can be used to accommodate for the intrinsic variability of wind and solar complementing opportunities for storage of power by batteries and pumped hydro. The green source of hydrogen can be used also to supplant current industrial uses of gray hydrogen produced in the Indian context largely from natural gas with important related emissions of CO2. The paper explores further options for use of green hydrogen to lower emissions from otherwise difficult to abate sectors of both industry and transport. The analysis is applied to identify the least cost options to meet India’s zero carbon future.
Ziwen Ruan, Xi Lu, Shuxiao Wang, Jia Xing, Wei Wang, Dan Chen, Chris P. Nielsen, Yong Luo, Kebin He, and Jiming Hao. 2022. “Impacts of large-scale deployment of mountainous wind farms on wintertime regional air quality in the Beijing-Tian-Hebei area.” Atmospheric Environment, 278, June, Pp. 119074. Publisher's VersionAbstract
The development of wind power plays an essential role in achieving China's carbon neutrality goals and air quality standards. A large number of studies have addressed the benefits of substituting fossil fuels with wind power on climate and air quality (defined as indirect impact) by macro-scale methodology. In recent years, more and more researchers have discussed its impacts on the general atmospheric circulation and air pollution dispersion (defined as direct impact) by parameterizing wind energy extraction in meso-micro scale models. However, the comprehensive investigation (considering both direct and indirect impacts) of the utilization of wind power on atmosphere environmental impacts remains vacant. Our study first evaluated both the direct and indirect impacts of wind power on air quality through an integrated methodological framework by using WRF-CMAQ system. The present analysis took wind farms located in Zhangjiakou to explore their impacts on air quality in winter, particularly over the downwind Beijing municipal area in the North China Plain. Results indicated that the deployment of wind power leads to spatially mixed direct impacts on PM2.5 concentrations in Beijing with a monthly net increase of 0.067 μg/m3 (0.08%) relative to the regional average. Contrarily, the substitution of coal-burning with wind power in rural household heating would result in notable indirect benefits to monthly PM2.5 concentrations in Beijing, specifically, reducing emissions of CO2 and conventional air pollutants by 64% in rural heating sector. The combined impacts of wind power displayed regional differences: in the wintertime (January), Zhangjiakou PM2.5 concentrations increased (+0.147 μg/m3) whereas, decreases are achieved (−5.642 μg/m3) in Beijing. Therefore, to support the large-scale deployment of wind power, future energy policies should take comprehensive account of the diverse environmental impacts, including both the indirect benefits of fossil energy substitution and the potential direct atmospheric effects on regional air quality.
Shi Chen, Xi Lu, Chris P. Nielsen, Guannan Geng, Michael B. McElroy, Shuxiao Wang, and Jiming Hao. 2022. “Improved air quality in China can enhance solar power performance and accelerate carbon neutrality targets.” One Earth, 5, 5, Pp. 550-562. Publisher's VersionAbstract
China forecasts that a 14-fold increase in photovoltaic installations is needed to meet 2060 carbon-neutrality targets. In light of the fact that air pollution impairs photovoltaic performance, pollution control could reduce the installation requirement, but research has not yet taken into account the coeval impact of unfavorable meteorological conditions, which also impair performance. Here, we employ a coupled model to determine the impact of air-pollution control policies on China’s photovoltaic power output in the presence of varying meteorological conditions between 1995 and 2019. We find that the benefits of air-pollution control introduced in 2004 were only partially offset by unfavorable meteorological conditions (primarily in Central and South China) and resulted in solar-power performance improvement of 0.9%/decade from 2008 onward. Further analysis shows that solar-power output in 2020 was 1.7% higher thanks to air-pollution control and that more stringent air-quality targets could reduce the demand for photovoltaic installed capacity needed to meet the 2060 carbon-neutrality target.
Peter Sherman, Haiyang Lin, and Michael B. McElroy. 2022. “Projected global demand for air conditioning associated with extreme heat and implications for electricity grids in poorer countries.” Energy and Buildings, 268, August, Pp. 112198. Publisher's VersionAbstract

Human-induced climate change will increase surface temperatures globally over the next several decades. Climate models project that global mean surface temperature could increase by over 2˚C by 2050 relative to the preindustrial period, with even greater changes at the regional level. These temperature changes have clear and pertinent implications for extremes, and consequentially, heat-induced health issues for people living in particularly hot climates. Here, we study future projections in the demand for AC globally in the 2050s associated with extreme heat events. To do this, we employ an ensemble of CMIP6 models under high and low emissions scenarios. We find that the increasing frequency of extreme temperatures will cause a significant portion of the global population to be exposed to conditions that require cooling. This issue will be especially pervasive in poor countries such as India and Indonesia, which at present lack the AC units required to handle rapidly growing populations and increased frequencies of extreme temperatures. The electricity needed for cooling in these countries could reach as high as 75% of the current total annual electricity demand, which could place serious strain on the electricity grid infrastructure during peak cooling hours. We conclude that demand for cooling in the future will pose a significant challenge for poorer countries whose people will require AC units to handle extreme temperatures. In some countries, the grid infrastructure is insufficient at present to meet projected AC demands, and this need must be considered in future power systems planning.

Shaodan Huang, Shaojie Song, Chris P. Nielsen, Yuqiang Zhang, Jianyin Xiong, Louise B. Weschler, Shaodong Xie, and Jing Li. 2022. “Residential building materials: An important source of ambient formaldehyde in mainland China.” Environment International, 158, January, Pp. 106909. Publisher's VersionAbstract
This study investigates the contribution of formaldehyde from residential building materials to ambient air in mainland China. Based on 265 indoor field tests in 9 provinces, we estimate that indoor residential sources are responsible for 6.66% of the total anthropogenic formaldehyde in China’s ambient air (range for 31 provinces: 1.88–18.79%). Residential building materials rank 6th among 81 anthropogenic sources (range: 2nd–10th for 31 provinces). Emission intensities show large spatial variability between and within regions due to different residential densities, emission characteristics of building materials, and indoor thermal conditions. Our findings indicate that formaldehyde from the indoor environment is a significant source of ambient formaldehyde, especially in urban areas. This study will help to more accurately evaluate exposure to ambient formaldehyde and its related pollutants, and will assist in formulating policies to protect air quality and public health.
2021
Xi Lu, Shi Chen, Chris P. Nielsen, Chongyu Zhang, Jiacong Li, Xu He, Ye Wu, Shuxiao Wang, Feng Song, Chu Wei, Kebin He, Michael P. McElroy, and Jiming Hao. 2021. “Combined solar power and storage as cost-competitive and grid-compatible supply for China’s future carbon-neutral electricity system.” Proceedings of the National Academy of Sciences, 118, October, Pp. 42. Publisher's VersionAbstract

As the world’s largest CO2 emitter, China’s ability to decarbonize its energy system strongly affects the prospect of achieving the 1.5 °C limit in global, average surface-temperature rise. Understanding technically feasible, cost-competitive, and grid-compatible solar photovoltaic (PV) power potentials spatiotemporally is critical for China’s future energy pathway. This study develops an integrated model to evaluate the spatiotemporal evolution of the technology-economic-grid PV potentials in China during 2020 to 2060 under the assumption of continued cost degression in line with the trends of the past decade. The model considers the spatialized technical constraints, up-to-date economic parameters, and dynamic hourly interactions with the power grid. In contrast to the PV production of 0.26 PWh in 2020, results suggest that China’s technical potential will increase from 99.2 PWh in 2020 to 146.1 PWh in 2060 along with technical advances, and the national average power price could decrease from 4.9 to 0.4 US cents/kWh during the same period. About 78.6% (79.7 PWh) of China’s technical potential will realize price parity to coal-fired power in 2021, with price parity achieved nationwide by 2023. The cost advantage of solar PV allows for coupling with storage to generate cost-competitive and grid-compatible electricity. The combined systems potentially could supply 7.2 PWh of grid-compatible electricity in 2060 to meet 43.2% of the country’s electricity demand at a price below 2.5 US cents/kWh. The findings highlight a crucial energy transition point, not only for China but for other countries, at which combined solar power and storage systems become a cheaper alternative to coal-fired electricity and a more grid-compatible option.

Lu et al. is the cover article of this October issue of PNAS. Read the Research Brief.
Xinyu Chen, Yaxing Liu, Qin Wang, Jiajun Lv, Jinyu Wen, Xia Chen, Chongqing Kang, Shijie Cheng, and Michael McElroy. 2021. “Pathway toward carbon-neutral electrical systems in China by mid-century with negative CO2 abatement costs informed by high-resolution modeling.” Joule, 5, 10 (20 October), Pp. 2715-2741. Publisher's VersionAbstract
China, the largest global CO2 emitter, recently announced ambitious targets for carbon neutrality by 2060. Its technical and economic feasibility is unclear given severe renewable integration barriers. Here, we developed a cross-sector, high-resolution assessment model to quantify optimal energy structures on provincial bases for different years. Hourly power system simulations for all provinces for a full year are incorporated on the basis of comprehensive grid data to quantify the renewable balancing costs. Results indicate that the conventional strategy of employing local wind, solar, and storage to realize 80% renewable penetration by 2050 would incur a formidable decarbonization cost of $27/ton despite lower levelized costs for renewables. Coordinated deployment of renewables, ultra-high-voltage transmissions, storages, Power-to-gas and slow-charging electric vehicles can reduce this carbon abatement cost to as low as $−25/ton. Were remaining emissions removed by carbon capture and sequestration technologies, achieving carbon neutrality could be not only feasible but also cost-competitive post 2050.
Jonathan D'Souza, Felix Prasanna, Luna-Nefeli Valayannopoulos-Akrivou, Peter John Sherman, Elise Penn, Shaojie Song, Alexander Archibald, and Michael B McElroy. 2021. “Projected changes in seasonal and extreme summertime temperature and precipitation in India in response to COVID-19 recovery emissions scenarios.” Environmental Research Letters. Publisher's VersionAbstract
Fossil fuel and aerosol emissions have played important roles on climate over the Indian subcontinent over the last century. As the world transitions toward decarbonization in the next few decades, emissions pathways could have major impacts on India's climate and people. Pathways for future emissions are highly uncertain, particularly at present as countries recover from COVID-19. This paper explores a multimodel ensemble of Earth system models leveraging potential global emissions pathways following COVID-19 and the consequences for India's summertime (June-July-August-September) climate in the near- and long-term. We investigate specifically scenarios which envisage a fossil-based recovery, a strong renewable-based recovery and a moderate scenario in between the two. We find that near-term climate changes are dominated by natural climate variability, and thus likely independent of the emissions pathway. By 2050, pathway-induced spatial patterns in the seasonally-aggregated precipitation become clearer with a drying in the fossil-based scenario and wetting in the strong renewable scenario. Additionally, extreme temperature and precipitation events in India are expected to increase in magnitude and frequency regardless of the emissions scenario, though the spatial patterns of these changes as well as the extent of the change are pathway dependent. This study provides an important discussion on the impacts of emissions recover pathways following COVID-19 on India, a nation which is likely to be particularly susceptible to climate change over the coming decades.
Yan Zhang, Yu Zhao, Meng Gao, Xin Bo, and Chris P. Nielsen. 2021. “Air quality and health benefits from ultra-low emission control policy indicated by continuous emission monitoring: a case study in the Yangtze River Delta region, China.” Atmospheric Chemistry and Physics, 21, Pp. 6411–6430. Publisher's VersionAbstract
To evaluate the improved emission estimates from online monitoring, we applied the Models-3/CMAQ (Community Multiscale Air Quality) system to simulate the air quality of the Yangtze River Delta (YRD) region using two emission inventories with and without incorporated data from continuous emission monitoring systems (CEMSs) at coal-fired power plants (cases 1 and 2, respectively). The normalized mean biases (NMBs) between the observed and simulated hourly concentrations of SO2, NO2, O3, and PM2.5 in case 2 were −3.1 %, 56.3 %, −19.5 %, and −1.4 %, all smaller in absolute value than those in case 1 at 8.2 %, 68.9 %, −24.6 %, and 7.6 %, respectively. The results indicate that incorporation of CEMS data in the emission inventory reduced the biases between simulation and observation and could better reflect the actual sources of regional air pollution. Based on the CEMS data, the air quality changes and corresponding health impacts were quantified for different implementation levels of China's recent “ultra-low” emission policy. If the coal-fired power sector met the requirement alone (case 3), the differences in the simulated monthly SO2, NO2, O3, and PM2.5 concentrations compared to those of case 2, our base case for policy comparisons, would be less than 7 % for all pollutants. The result implies a minor benefit of ultra-low emission control if implemented in the power sector alone, which is attributed to its limited contribution to the total emissions in the YRD after years of pollution control (11 %, 7 %, and 2 % of SO2, NOX, and primary particle matter (PM) in case 2, respectively). If the ultra-low emission policy was enacted at both power plants and selected industrial sources including boilers, cement, and iron and steel factories (case 4), the simulated SO2, NO2, and PM2.5concentrations compared to the base case would be 33 %–64 %, 16 %–23 %, and 6 %–22 % lower, respectively, depending on the month (January, April, July, and October 2015). Combining CMAQ and the Integrated Exposure Response (IER) model, we further estimated that 305 deaths and 8744 years of life loss (YLL) attributable to PM2.5 exposure could be avoided with the implementation of the ultra-low emission policy in the power sector in the YRD region. The analogous values would be much higher, at 10 651 deaths and 316 562 YLL avoided, if both power and industrial sectors met the ultra-low emission limits. In order to improve regional air quality and to reduce human health risk effectively, coordinated control of multiple sources should be implemented, and the ultra-low emission policy should be substantially expanded to major emission sources in industries other than the power industry.
Jinzhao Yang, Yu Zhao, Jing Cao, and Chris P. Nielsen. 2021. “Co-benefits of carbon and pollution control policies on air quality and health till 2030 in China.” Environment International, 152, July, Pp. 106482. Publisher's VersionAbstract
Facing the dual challenges of climate change and air pollution, China has made great efforts to explore the co-control strategies for the both. We assessed the benefits of carbon and pollution control policies on air quality and human health, with an integrated framework combining an energy-economic model, an air quality model and a concentration–response model. With a base year 2015, seven combined scenarios were developed for 2030 based on three energy scenarios and three end-of-pipe control ones. Policy-specific benefits were then evaluated, indicated by the reduced emissions, surface concentrations of major pollutants, and premature deaths between scenarios. Compared to the 2030 baseline scenario, the nationwide PM2.5- and O3-related mortality was expected to decline 23% or 289 (95% confidence interval: 220–360) thousand in the most stringent scenario, and three quarters of the avoided deaths were attributed to the end-of-pipe control measures. Provinces in heavily polluted and densely populated regions would benefit more from carbon and pollution control strategies. The population fractions with PM2.5 exposure under the national air quality standard (35 μg/m3) and WHO guideline (10 μg/m3) would be doubled from 2015 to 2030 (the most stringent scenario), while still very few people would live in areas with the WHO guideline achieved for O3 (100 μg/m3). Increased health impact of O3 suggested a great significance of joint control of PM2.5 and O3 in future policy-making.
Xi Yang, Jun Pang, Fei Teng, Ruixin Gong, and Cecilia Springer. 2021. “The environmental co-benefit and economic impact of China’s low-carbon pathways: Evidence from linking bottom-up and top-down models.” Renewable and Sustainable Energy Reviews, 136, February, Pp. 110438. Publisher's VersionAbstract
Deep decarbonization pathways (DDPs) can be cost-effective for carbon mitigation, but they also have environmental co-benefits and economic impacts that cannot be ignored. Despite many empirical studies on the co-benefits of NDCs at the national or sectoral level, there is lack of integrated assessment on DDPs for their energy, economic, and environmental impact. This is due to the limitations of bottom-up and top-down models when used alone. This paper aims to fill this gap and link the bottom-up MAPLE model with a top-down CGE model to evaluate China's DDPs' comprehensive impacts. First, results show that carbon dioxide emissions can be observed to peak in or before 2030, and non-fossil energy consumption in 2030 is around 27%, which is well above the NDC target of 20%. Second, significant environmental co-benefits can be expected: 7.1 million tons of SO2, 3.96 million tons of NOx, and 1.02 million tons of PM2.5 will be reduced in the DDP scenario compared to the reference scenario. The health co-benefits demonstrated with the model-linking approach is around 678 billion RMB, and we observe that the linked model results are more in accordance with the conclusions of existing studies. Third, after linking, we find the real GDP loss from deep decarbonization is reduced from 0.92% to 0.54% in 2030. If the environmental co-benefits are considered, the GDP loss is further offset by 0.39%. The primary innovation of this study is to give a full picture of DDPs' impact, considering both environmental co-benefits and economic losses. We aim to provide positive evidence that developing countries can achieve targets higher than stated in the NDCs through DDP efforts, which will have clear environmental co-benefits to offset the economic losses.
Shaojie Song, Tao Ma, Yuzhong Zhang, Lu Shen, Pengfei Liu, Ke Li, Shixian Zhai, Haotian Zheng, Meng Gao, Jonathan M. Moch, Fengkui Duan, Kebin He, and Michael B. McElroy. 2021. “Global modeling of heterogeneous hydroxymethanesulfonate chemistry.” Atmospheric Chemistry and Physics, 21, 1, Pp. 457–481. Publisher's VersionAbstract
Hydroxymethanesulfonate (HMS) has recently been identified as an abundant organosulfur compound in aerosols during winter haze episodes in northern China. It has also been detected in other regions although the concentrations are low. Because of the sparse field measurements, the global significance of HMS and its spatial and seasonal patterns remain unclear. Here, we modify and add to the implementation of HMS chemistry in the GEOS-Chem chemical transport model and conduct multiple global simulations. The model accounts for cloud entrainment and gas–aqueous mass transfer within the rate expressions for heterogeneous sulfur chemistry. Our simulations can generally reproduce quantitative HMS observations from Beijing and show that East Asia has the highest HMS concentration, followed by Europe and North America. The simulated HMS shows a seasonal pattern with higher values in the colder period. Photochemical oxidizing capacity affects the competition of formaldehyde with oxidants (such as ozone and hydrogen peroxide) for sulfur dioxide and is a key factor influencing the seasonality of HMS. The highest average HMS concentration (1–3 µg m−3) and HMS ∕ sulfate molar ratio (0.1–0.2) are found in northern China in winter. The simulations suggest that aqueous clouds act as the major medium for HMS chemistry while aerosol liquid water may play a role if its rate constant for HMS formation is greatly enhanced compared to cloud water.
Minghao Zhuang, Xi Lu, Wei Peng, Yanfen Wang, Jianxiao Wang, Chris P. Nielsen, and Michael B. McElroy. 2021. “Opportunities for household energy on the Qinghai-Tibet Plateau in line with United Nations’ Sustainable Development Goals.” Renewable and Sustainable Energy Reviews, 144, July, Pp. 110982. Publisher's VersionAbstract
Approximately seven million population in the Qinghai-Tibet Plateau of China, a global climate sensitive region, still rely primarily on yak dung for household cooking and heating. The treatment and combustion of yak dung result in a variety of negative impacts in terms of local alpine grassland degradation, indoor air pollution, public health risk, as well as global climate change. There is an urgent need to explore alternative pathway for affordable and clean energy as indicated in the United Nations’ Sustainable Development Goals for 2030. This perspective has analyzed the key challenges rooted in yak dung use on the Qinghai-Tibet Plateau region. Based on this, this perspective has further proposed a new complementary energy system to take advantage of locally available, clean and sustainable energy sources of wind and solar power, and have provided economic analyses. Meanwhile, this perspective has pointed out the potential barriers to promoting the new complementary energy system in the Qinghai-Tibet Plateau region due to traditional habits, economic factors and policies. Finally, strategies for transitioning from yak dung to the proposed alternative energy system is discussed at the end. Successful energy transition for the Qinghai-Tibet Plateau region offers an important option to achieving many other sustainable development goals related to climate change, economic development, and environment. The perspective is expected to shed light on the development of sustainable energy in other developing region or countries in the world to address multiple societal goals.
Peter Sherman, Shaojie Song, Xinyu Chen, and Michael B. McElroy. 2021. “Projected changes in wind power potential over China and India in high resolution climate models.” Environmental Research Letters, 16, 3, Pp. 034057. Publisher's VersionAbstract
As more countries commit to emissions reductions by midcentury to curb anthropogenic climate change, decarbonization of the electricity sector becomes a first-order task in reaching this goal. Renewables, particularly wind and solar power, will be predominant components of this transition. How availability of the wind and solar resource will change in the future in response to regional climate changes is an important and underdiscussed topic of the decarbonization process. Here, we study changes in potential for wind power in China and India, evaluating prospectively until the year 2060. To do this, we study a downscaled, high-resolution multimodel ensemble of CMIP5 models under high and low emissions scenarios. While there is some intermodel variability, we find that spatial changes are generally consistent across models, with decreases of up to 965 (a 1% change) and 186 TWh (a 2% change) in annual electricity generation potential for China and India, respectively. Compensating for the declining resource are weakened seasonal and diurnal variabilities, allowing for easier large-scale wind power integration. We conclude that while the ensemble indicates available wind resource over China and India will decline slightly in the future, there remains enormous potential for significant wind power expansion, which must play a major role in carbon neutral aspirations.
Qing Yang, Hewen Zhou, Pietro Bartocci, Francesco Fantozzi, Ondřej Mašek, Foster Agblevor, Zhiyu Wei, Haiping Yang, Hanping Chen, Xi Lu, Guoqian Chen, Chuguang Zheng, Chris Nielsen, and Michael McElroy. 2021. “Prospective contributions of biomass pyrolysis to China’s 2050 carbon reduction and renewable energy goals.” Nature Communications, 12, 168. Publisher's VersionAbstract
Deployment of negative emission technologies needs to start immediately if we are to avoid overshooting international carbon targets, reduce negative climate impacts, and minimize costs of emission mitigation. Actions in China, given its importance for the global anthropogenic carbon budget, can be decisive. While bioenergy with carbon capture and storage (BECCS) may need years to mature, this study focuses on developing a ready-to-implement biomass intermediate pyrolysis poly-generation (BIPP) technology to produce a potentially stable form of biochar, a medium for carbon storage, and to provide a significant source of valuable biofuels, especially pyrolysis gas. Combining the experimental data with hybrid models, the results show that a BIPP system can be profitable without subsidies: its national deployment could contribute to a 68% reduction of carbon emissions per unit of GDP in 2030 compared to 2005 and could result additionally in a reduction in air pollutant emissions. With 73% of national crop residues converted to biochar and other biofuels in the near term (2020 to 2030), the cumulative greenhouse gas (GHG) reduction could reach up to 5653 Mt CO2-eq by 2050, which could contribute 9-20% of the global GHG emission reduction goal for BECCS (28-65 Gt CO2-eq in IPCC’s 1.5 °C pathway), and nearly 2633 Mt more than that projected for BECCS alone. The national BIPP development strategy is developed on a provincial scale based on a regional economic and life-cycle analysis. 
Peter Sherman, Meng Gao, Shaojie Song, Alex T. Archibald, Nathan Luke Abraham, Jean-François Lamarque, Drew Shindell, Gregory Faluvegi, and Michael B. McElroy. 2021. “Sensitivity of modeled Indian Monsoon to Chinese and Indian aerosol emissions.” Atmospheric Chemistry and Physics, 21, 5, Pp. 3593–3605. Publisher's VersionAbstract
The South Asian summer monsoon supplies over 80 % of India's precipitation. Industrialization over the past few decades has resulted in severe aerosol pollution in India. Understanding monsoonal sensitivity to aerosol emissions in general circulation models (GCMs) could improve predictability of observed future precipitation changes. The aims here are (1) to assess the role of aerosols on India's monsoon precipitation and (2) to determine the roles of local and regional emissions. For (1), we study the Precipitation Driver Response Model Intercomparison Project experiments. We find that the precipitation response to changes in black carbon is highly uncertain with a large intermodel spread due in part to model differences in simulating changes in cloud vertical profiles. Effects from sulfate are clearer; increased sulfate reduces Indian precipitation, a consistency through all of the models studied here. For (2), we study bespoke simulations, with reduced Chinese and/or Indian emissions in three GCMs. A significant increase in precipitation (up to ~ 20 %) is found only when both countries' sulfur emissions are regulated, which has been driven in large part by dynamic shifts in the location of convective regions in India. These changes have the potential to restore a portion of the precipitation losses induced by sulfate forcing over the last few decades.
2020
Haotian Zheng, Shaojie Song, Golam Sarwar, Masao Gen, Shuxiao Wang, Dian Ding, Xing Chang, Shuping Zhang, Jia Xing, Yele Sun, Dongsheng Ji, Chak Chan, Jian Gao, and Michael B. McElroy. 2020. “Contribution of particulate nitrate photolysis to heterogeneous sulfate formation for winter haze in China.” Environmental Science & Technology Letters , 7, 9, Pp. 632–638. Publisher's VersionAbstract
Nitrate and sulfate are two key components of airborne particulate matter (PM). While multiple formation mechanisms have been proposed for sulfate, current air quality models commonly underestimate its concentrations and mass fractions during northern China winter haze events. On the other hand, current models usually overestimate the mass fractions of nitrate. Very recently, laboratory studies have proposed that nitrous acid (N(III)) produced by particulate nitrate photolysis can oxidize sulfur dioxide to produce sulfate. Here, for the first time, we parameterize this heterogeneous mechanism into the state-of-the-art Community Multi-scale Air Quality (CMAQ) model and quantify its contributions to sulfate formation. We find that the significance of this mechanism mainly depends on the enhancement effects (by 1–3 orders of magnitude as suggested by the available experimental studies) of nitrate photolysis rate constants in aerosol liquid water compared to that in the gas phase. Comparisons between model simulations and in-situ observations in Beijing suggest that this pathway can explain about 15% (assuming an enhancement factor (EF) of 10) to 65% (assuming EF = 100) of the model–observation gaps in sulfate concentrations during winter haze. Our study strongly calls for future research on reducing the uncertainty in EF.
X. Lu, L. Zhang, T. Wu, M. S. Long, J. Wang, D.J. Jacob, F. Zhang, J. Zhang, S. D. Eastham, L. Hu, L. Zhu, X. Liu, and M. Wei. 2020. “Development of the global atmospheric general circulation-chemistry model BCC-GEOS-Chem v1.0: model description and evaluation.” Geoscientific Model Development, 13, 9, Pp. 3817–3838. Publisher's VersionAbstract
Chemistry plays an indispensable role in investigations of the atmosphere; however, many climate models either ignore or greatly simplify atmospheric chemistry, limiting both their accuracy and their scope. We present the development and evaluation of the online global atmospheric chemical model BCC-GEOS-Chem v1.0, coupling the GEOS-Chem chemical transport model (CTM) as an atmospheric chemistry component in the Beijing Climate Center atmospheric general circulation model (BCC-AGCM). The GEOS-Chem atmospheric chemistry component includes detailed troposphericHOx–NOx–volatile organic compounds–ozone–bromine–aerosol chemistry and online dry and wet deposition schemes. We then demonstrate the new capabilities of BCC-GEOS-Chem v1.0 relative to the base BCC-AGCM model through a 3-year (2012–2014) simulation with anthropogenic emissions from the Community Emissions Data System (CEDS) used in the Coupled Model Intercomparison Project Phase 6 (CMIP6). The model captures well the spatial distributions and seasonal variations in tropospheric ozone, with seasonal mean biases of 0.4–2.2 ppbv at 700–400 hPa compared to satellite observations and within 10 ppbv at the surface to 500 hPa compared to global ozonesonde observations. The model has larger high-ozone biases over the tropics which we attribute to an overestimate of ozone chemical production. It underestimates ozone in the upper troposphere which is likely due either to the use of a simplified stratospheric ozone scheme or to biases in estimated stratosphere–troposphere exchange dynamics. The model diagnoses the global tropospheric ozone burden, OH concentration, and methane chemical lifetime to be 336 Tg, 1.16×106 molecule cm−3, and 8.3 years, respectively, which is consistent with recent multimodel assessments. The spatiotemporal distributions of NO2, CO, SO2, CH2O, and aerosol optical depth are generally in agreement with satellite observations. The development of BCC-GEOS-Chem v1.0 represents an important step for the development of fully coupled earth system models (ESMs) in China.

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